Triacetoxyperiodinane → HCID 49820162, compound

Participants

Reaction Steps

To a solution of compound 7d (50 mg, 0.12 mmol) in DMSO (1.5 mL) was added Dess-Martin periodinane (100 mg, 0.24 mmol) at 0° C. The resulting mixture was stirred at room temperature for 20 min and poured into ice water (2 mL). The resulting precipitate was filtered, washed with water, and dried under high vacuum to obtain compound SKC-BF-07 (25 mg, 55%) as a red solid. TLC Rf=0.45 (petroleum ether-EtOAc, 6:4); 1H NMR (CDCl3) δ 7.89 (s, 1H), 7.85 (d, J=8.7 Hz, 2H), 6.95 (d, J=9.0 Hz, 2H), 6.78 (s, 1H), 3.89 (s, 3H); MS (ES) m/z 362 (M+H)+.

Provenance & Evidence