Triacetoxyperiodinane → HCID 49820159, compound

Participants

Reaction Steps

To a solution of compound 10e (100 mg, 0.29 mmol) in DMSO (1.5 mL) was added Dess-Martin periodinane (253 mg, 0.59 mmol) at 0° C. The resulting mixture was stirred at room temperature for 20 min and poured into ice-water (2 mL). The resulting precipitate was filtered, washed with water, and dried under high vacuum to obtain compound SKC-BF-03 (50 mg, 53%) as an orange solid. TLC Rf=0.5 (petroleum ether-EtOAc, 6:4); 1H NMR (CDCl3) δ 7.90-7.84 (m, 3H), 6.95 (d, J=8.6 Hz, 2H), 6.53 (s, 1H), 3.88 (s, 3H); MS (ES) m/z 317 (M+H)+.

Provenance & Evidence