HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl iodide → 9-Methylfluorene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl iodide | HCID 6328 | — |
| Reactant | Fluorene | HCID 6853 | — |
| Reactant | L-Altrose | HCID 10219674 | — |
| Reactant | Butyllithium | HCID 178418339 | — |
| Product | 9-Methylfluorene | HCID 17299 | — |
Reaction Steps
Fluorene (15.0 g, 90.4 mmol), n-BuLi (48.1 ml, 120 mmol, 2.5 M in hexane), RX=iodomethane (19.3 g, 136 mmol). 40 was isolated as a yellowish waxy solid (16.2 g, quant.). The analytical data were identical to those in the literature (M. A. Schmidt, H. G. Alt, W. Milius, J. Organomet. Chem. 1996, 525, 15).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08618328B2 |
| Source dataset | uspto-grants-2013_12 |
| ORD ID | ord-4345399dd4d14219a53ce9a4c1f77ef7 |
| Source note | uspto-grants-2013_12 |