HuagongsheHuagongshe Chemistry Print Report · For research reference only
Fluorene → 9-Propyl-9H-fluorene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Fluorene | HCID 6853 | — |
| Reactant | 1-Iodopropane | HCID 33643 | — |
| Reactant | Butyllithium | HCID 178418339 | — |
| Product | 9-Propyl-9H-fluorene | HCID 178017 | — |
Reaction Steps
Fluorene (15.0 g, 90.4 mmol), n-BuLi (48.1 ml, 120 mmol, 2.5 M in hexane), RX=1-iodopropane (20.8 g, 122.3 mmol). 43 was isolated as a yellowish solid (18.6 g, quant.). The analytical data were identical to those found in the literature (A. Mathieu, Bull. Soc. Chim. Fr. 1971, 1526).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08618328B2 |
| Source dataset | uspto-grants-2013_12 |
| ORD ID | ord-a7996807f8de462191a1b00ce1779294 |
| Source note | uspto-grants-2013_12 |