Cyclohexanone, 4,4-dimethyl- → 2-(Diethoxymethyl)-4,4-dimethylcyclohexanone

HRID 1920362Notes

Reaction equation

HRID 1920362 reaction equation
[CH3:1][C:2]1([CH3:9])[CH2:7][CH2:6][C:5](=[O:8])[CH2:4][CH2:3]1.F[B-](F)(F)F.[CH2:15]([O:17][CH+:18][O:19][CH2:20][CH3:21])[CH3:16]>>[CH2:15]([O:17][CH:18]([O:19][CH2:20][CH3:21])[CH:4]1[CH2:3][C:2]([CH3:9])([CH3:1])[CH2:7][CH2:6][C:5]1=[O:8])[CH3:16]

Participants

3

Reactant 2

HCID 138166Cyclohexanone, 4,4-dimethyl-HCID 178468207HCID 178468207, compound

Product 1

HCID 580183412-(Diethoxymethyl)-4,4-dimethylcyclohexanone

Procedure

reacting 4,4-dimethylcyclohexanone, diethoxycarbenium fluoroborate and a fifth base to provide (2-(diethoxymethyl)-4,4-dimethylcyclohexanone and isolating or not isolating the 2-(diethoxymethyl)-4,4-dimethylcyclohexanone;

Sources & evidence

ORD record
ord-48d4a885542e436ca518e7ee5d301f82
Source dataset
uspto-grants-2012_05
Patent number
US08168784B2

Reaction notes

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