HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl 4-[5-[1-(2-ethoxy-2-oxoethyl)cyclopropyl]-3-(hydroxymethyl)pentyl]benzoate → Methyl 4-{5-[1-(2-ethoxy-2-oxoethyl)cyclopropyl]-3-formylpentyl}benzoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl 4-[5-[1-(2-ethoxy-2-oxoethyl)cyclopropyl]-3-(hydroxymethyl)pentyl]benzoate | HCID 57965773 | — |
| Reactant | HCID 178418287 | HCID 178418287 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | Methyl 4-{5-[1-(2-ethoxy-2-oxoethyl)cyclopropyl]-3-formylpentyl}benzoate | HCID 57965765 | — |
Reaction Steps
235.5 mg (1.09 mmol) of pyridinium chlorochromate (PCC) are added to a solution of 330 mg (0.91 mmol) of methyl 4-[5-[1-(2-ethoxy-2-oxoethyl)cyclopropyl]-3-(hydroxymethyl)pentyl]-benzoate in 30 ml of dichloromethane, and the mixture is stirred at room temperature for 12 hours.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08168821B2 |
| Source dataset | uspto-grants-2012_05 |
| ORD ID | ord-f1598267d636439c91d6014ac4098fd9 |
| Source note | uspto-grants-2012_05 |