3-(1H-Imidazol-1-ylsulfonyl)-1-methyl-1H-imidazolium trifluoromethanesulfonate → HCID 68911353, compound

HRID 1928789Notes

Reaction equation

HRID 1928789 reaction equation
Cl.[C@H:2]12[CH2:8][CH:5]([NH:6][CH2:7]1)[CH2:4][O:3]2.FC(F)(F)S([O-])(=O)=O.[N:17]1([S:22](N2C=C[NH+](C)C2)(=[O:24])=[O:23])[CH:21]=[CH:20][N:19]=[CH:18]1>>[N:17]1([S:22]([N:6]2[CH2:7][C@@H:2]3[CH2:8][C@H:5]2[CH2:4][O:3]3)(=[O:24])=[O:23])[CH:21]=[CH:20][N:19]=[CH:18]1

Participants

3

Reactant 2

HCID 866341663-(1H-Imidazol-1-ylsulfonyl)-1-methyl-1H-imidazolium trifluoromethanesulfonateHCID 86634175HCID 86634175, compound

Product 1

HCID 68911353HCID 68911353, compound

Procedure

(1S,4S)-5-(Imidazole-1-sulfonyl)-2-oxa-5-aza-bicyclo[2.2.1]heptane was prepared in accordance with step A of the general method described in example 76 from all-(S)-(+)-2-oxa-5-aza-bicyclo[2.2.1]heptane hydrochloride and 3-(1H-imidazol-1-ylsulfonyl)-1-methyl-1H-imidazolium trifluoromethanesulfonate; MS: m/e=230.5 (M+H−).

Sources & evidence

ORD record
ord-e2d406f802d14bffafa3814f8d9dc4e9
Source dataset
uspto-grants-2012_05
Patent number
US08183380B2

Reaction notes

Loading…