Cyclohexanone → 1-Hydroxycyclohexyl phenyl ketone

HRID 1929270Notes

Reaction equation

HRID 1929270 reaction equation
[C:1]1(=[O:7])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[C:8]1(=O)[O:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9]1.[C:16]([O-])(=O)C=C>>[CH2:4]1[CH2:5][CH2:6][C:1]([OH:7])([C:13]([C:12]2[CH:11]=[CH:10][CH:9]=[CH:8][CH:16]=2)=[O:14])[CH2:2][CH2:3]1

Participants

4

Reactant 3

HCID 7967CyclohexanoneHCID 10401epsilon-CAPROLACTONEHCID 25188Acrylate

Product 1

HCID 703551-Hydroxycyclohexyl phenyl ketone

Procedure

10 Parts by mass of cyclohexanone, 95 parts by mass of partially caprolactone-modified polyfunctional acrylate (DPCA-20, produced by Nippon Kayaku Co., Ltd.), and 5 parts by mass of a photopolymerization initiator (Irgacure 184, produced by Ciba Specialty Chemicals Corp.) were added to 90 parts by mass of methyl ethyl ketone (MEK). The resulting mixture was stirred and then filtered through a polypropylene-made filter having a pore size of 0.4 μm to prepare Coating Solution (HCL-1) for Hardcoat Layer.

Sources & evidence

ORD record
ord-709c081f7bc2409381807a8d894fdbac
Source dataset
uspto-grants-2012_05
Patent number
US08187704B2

Reaction notes

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