Ammonia → HCID 86625133, compound

Participants

Reaction Steps

General procedure f from 17 (95%); colorless oil, recrystallization from EtOH gave white powder; mp 122-124° C.; 1H NMR (400.13 MHz) δ 8.13 (d, J=4 Hz, 1H), 7.90 (d, J=2 Hz, 1H), 7.84 (s, 1H), 7.51 (d, J=4 Hz, 2H), 7.42 (s, 1H), 7.41 (t, J=4 Hz, 2H), 7.34 (m, 1H), 7.29 (dd, J=4 Hz, 2 Hz, 1H), 7.14 (s, 1H), 6.06 (s, 2H), 5.24 (s, 2H), 4.36 (d, J=7 Hz, 2H), 3.78 (d, J=17 Hz, 2H), 3.41 (m, 1H), 2.42 (m, 2H), 1.83 (m, 2H), 1.66 (m, 6H); MS (DCI/NH3) m/e: 442 (M+H)+. Anal. (C28H27O4N) C, H, N.

Provenance & Evidence