Pyridine → HCID 57419452, compound

HRID 1930258Notes

Reaction equation

HRID 1930258 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]([CH:8]=[CH:9][C:10]=1[N+:11]([O-:13])=[O:12])[NH2:7])([O-:3])=[O:2].[CH3:14][S:15](Cl)(=[O:17])=[O:16].N1C=CC=CC=1>C(Cl)Cl>[N+:1]([C:4]1[CH:5]=[C:6]([NH:7][S:15]([CH3:14])(=[O:17])=[O:16])[CH:8]=[CH:9][C:10]=1[N+:11]([O-:13])=[O:12])([O-:3])=[O:2]

Participants

5

Reactant 3

HCID 1049PyridineHCID 31297Methanesulfonyl chlorideHCID 1364073,4-Dinitroaniline

Product 1

HCID 57419452HCID 57419452, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

A mixture of 3,4-dinitroaniline (5.27 g, 28.8 mmol), methanesulfonyl chloride (3.36 mL, 43.1 mmol) and pyridine (5.82 mL, 71.9 mmol) in CH2Cl2 (100 mL) was stirred for 24 h. Mixture was concentrated under vacuum to provide a crude semi-solid title compound that was used without further purification.

Workup

  1. concentrationMixture was concentrated under vacuum

Sources & evidence

ORD record
ord-52f1292cb89a4e20ba19d0d320e618f3
Source dataset
uspto-grants-2012_05
Patent number
US08188104B2

Reaction notes

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