p-Toluenesulfonic acid → HCID 22468308, compound

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Reaction Steps

To a stirred solution of 30 g of 1,1-dihydroperoxycyclohexane in ethylacetate was added 0.4 g p-toluene sulfonic acid. Then 19.6 g isobutyl vinyl ether were added in 10 min, the reaction temperature being kept at 20° C. by cooling with an ice-water bath. The mixture was stirred for 60 min. The mixture was washed with sodium bicarbonate solution and dried on MgSO4. Yield 35 g of product with an active oxygen content of 6.75% Chemical yield:67%.

Provenance & Evidence