HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1936977Generated: November 1, 2026
Sulfuric Acid → 3,5-Bis(tert-butyl)benzaldehyde
https://huagongshe.com/reaction/1936977
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Sulfuric Acid | HCID 1118 | — |
| Reactant | Hexamethylenetetramine | HCID 4101 | — |
| Reactant | Boric Acid | HCID 7628 | — |
| Reactant | 2,6-Di-tert-butylphenol | HCID 31405 | — |
| Reactant | 2,6-Di-tert-butyl-4-vinylphenol | HCID 12576680 | — |
| Solvent | Ethylene Glycol | HCID 174 | — |
| Product | 3,5-Bis(tert-butyl)benzaldehyde | HCID 1268253 | — |
Reaction Steps
3.5 g of boric acid was heated in 150 ml of ethylene glycol at 150° C. for 30 minutes, in a 500 cc flask equipped with a reflux condenser. 25 g of hexamethylenetetramine and 21 g of 2,6-bis (1,1-dimethylethyl)phenol were then added and the solution maintained at 148-150° C. for 15 minutes. After cooling to 125° C. at which stage the first crystals appeared, 150 ml of H2SO4 (30% 0 was added and stirring was continued for another 30 minutes. The resulting slurry was filtered and washed with warm water. After drying, 22 g of 3,5-bis (1,1-dimethylethyl)benzaldehyde was obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US06391951B1 |
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| Source dataset | uspto-grants-2002_05 |
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| ORD ID | ord-624274d5a5d3433dae79dd7bfc7b65a0 |
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| Source note | uspto-grants-2002_05 |
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