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Trichloro(chloromethyl)silane → Bis(trichlorosilyl)methane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Trichloro(chloromethyl)silane | HCID 15258 | — |
| 反応物 | Trichlorosilane | HCID 24811 | — |
| 反応物 | Benzyltributylphosphonium chloride | HCID 200231 | — |
| 生成物 | Bis(trichlorosilyl)methane | HCID 2756737 | 68% |
反応手順
In the same apparatus and procedure as Example 1 above, 0.22 g (0.67 mmol) of benzyltributylphosphonium chloride, 1.23 g (6.69 mmol) of (chloromethyl)trichlorosilane, and 2.71 g (20.0 mmol) of trichlorosilane were reacted at 160° C. for 15 hrs. The resulting mixture was distilled to give 1.13 g of 1,1,1,3,3,3-hexachloro-1,3-disilapropane (yield; 68%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06392077B1 |
| 出典データセット | uspto-grants-2002_05 |
| ORD ID | ord-02059802c52946f29da4856f0cad71a8 |
| 出典メモ | uspto-grants-2002_05 |