Benzyl Chloride → Benzene, [(trichlorosilyl)methyl]-

HRID 1937083Notes

Reaction equation

[CH2:1](Cl)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Cl:9][SiH:10]([Cl:12])[Cl:11]>>[CH2:1]([Si:10]([Cl:12])([Cl:11])[Cl:9])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

Reactant 2

HCID 7503Benzyl Chloride

HCID 24811Trichlorosilane

Product 1

HCID 69863Benzene, [(trichlorosilyl)methyl]-Yield 85%

Procedure

In the same apparatus and procedure as Example 1 above, 0.16 g (0.40 mmol) of ethylenebis(benzyldimethylphosphonium chloride), 1.00 g (7.90 mmol) of benzyl chloride, and 3.21 g (23.7 mmol) of trichlorosilane were reacted at 150° C. for 2 hrs. The resulting mixture was distilled to give 1.51 g of benzyltrichlorosilane (yield; 85%).

Workup

distillationThe resulting mixture was distilled

Sources & evidence

ORD record: ord-1bd657210e914b709f6b91e2cc39a646
Source dataset: uspto-grants-2002_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06392077B1

Reaction notes

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