(1-Chloroethyl)benzene → 1-Trichlorosilylethylbenzene

HRID 1937090Notes

Reaction equation

HRID 1937090 reaction equation
Cl[CH:2]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)[CH3:3].[Cl:10][SiH:11]([Cl:13])[Cl:12]>[Cl-].C([P+](CCCC)(CCCC)CCCC)CCC>[Cl:10][Si:11]([Cl:13])([Cl:12])[CH:2]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)[CH3:3]

Participants

4

Reactant 2

HCID 12648(1-Chloroethyl)benzeneHCID 24811Trichlorosilane

Product 1

HCID 117912891-TrichlorosilylethylbenzeneYield 35.4%

Reagents, catalysts & solvents 1

HCID 75311Tetrabutylphosphonium chlorideCatalyst

Procedure

In the same apparatus and procedure as Example 1 above, 0.20 g (0.68 mmol) of tetrabutylphosphonium chloride, 0.96 g (6.83 mmol) of 1-chloroethylbenzene, and 2.71 g (20.00 mmol) of trichlorosilane were reacted at 150° C. for 6 hrs. The resulting mixture was distilled to give 0.58 g 1-trichlorosilylethylbenzene (yield; 35%).

Workup

  1. distillationThe resulting mixture was distilled

Sources & evidence

ORD record
ord-7a8a7685ee9849e8b6cf0805d69bd095
Source dataset
uspto-grants-2002_05
Patent number
US06392077B1

Reaction notes

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