HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyltriphenylphosphonium iodide → HCID 69957465, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyltriphenylphosphonium iodide | HCID 638159 | — |
| Reactant | Sodium bis(trimethylsilyl)amide toluene | HCID 23702675 | — |
| Reactant | HCID 69957533 | HCID 69957533 | — |
| Product | HCID 69957465 | HCID 69957465 | 88% |
Reaction Steps
Similarly to Example 7, 6665.6 mg(5 equivalents) of methyltriphenylphosphonium iodide and 16.5 ml(5 equivalents) of sodium bis(trimethylsilyl)amide-toluene solution(1M) were reacted with 786.0 mg of (1R,3R,3aS,4aR,8aS,9aR)-1-methoxy-3-methyl-4-oxo-dodecahydronaphtho[2,3-c]furan to obtain 683.5 mg of (1R,3R,3aR,4aR,8aS,9aR)-1-methoxy-3-methyl-4-methylene-dodecahydronaphtho[2,3-c]furan(yield 88%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06392059B1 |
| Source dataset | uspto-grants-2002_05 |
| ORD ID | ord-c96bb7714d0e41af826dd1a01755d5c5 |
| Source note | uspto-grants-2002_05 |