化工社化工社 化学情報印刷レポート · 研究参考用
Oxygen → 1-Carboxy-3-nitro-5-adamantanol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Oxygen | HCID 977 | — |
| 反応物 | 3-Nitrotricyclo(3.3.1.13,7)decane-1-carboxylic acid | HCID 39239 | — |
| 溶媒 | Acetic Acid | HCID 176 | — |
| 生成物 | 1-Carboxy-3-nitro-5-adamantanol | HCID 22463570 | 80% |
反応手順
In an atmosphere of oxygen, the mixture of 10 mmole of 1-carboxy-3-nitroadamantane, 1 mmole of NHPI, 0.05 mmole of V(AA) 3 and 25 mL of acetic acid was allowed to react for 4 hours at 85° C. The reaction products were analyzed by gas-mass spectroscopy, and as a result, 1-carboxy-3-nitro-5-adamantanol was formed in a 80% yield.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06392104B1 |
| 出典データセット | uspto-grants-2002_05 |
| ORD ID | ord-32be10716b084944abeb66e5d07af09e |
| 出典メモ | uspto-grants-2002_05 |