Oxygen → HCID 10039509, compound

HRID 1937263Notes

Reaction equation

HRID 1937263 reaction equation
[O:1]=O.[C:3]([C:6]12[CH2:15][C:10]3([C:16]([OH:18])=[O:17])[CH2:11][CH:12]([CH2:14][C:8]([C:19]([OH:21])=[O:20])([CH2:9]3)[CH2:7]1)[CH2:13]2)([OH:5])=[O:4]>C(O)(=O)C>[C:16]([C:10]12[CH2:15][C:6]3([C:3]([OH:5])=[O:4])[CH2:13][C:12]([OH:1])([CH2:14][C:8]([C:19]([OH:21])=[O:20])([CH2:7]3)[CH2:9]1)[CH2:11]2)([OH:18])=[O:17]

Participants

4

Reactant 2

HCID 977OxygenHCID 754344213274-89-6

Product 1

HCID 10039509HCID 10039509, compoundYield 70%

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Conditions

Temperature
75 °C

Procedure

In an atmosphere of oxygen, to 25 mL of acetic acid was added 10 mmole of the 1,3,5-tricarboxyadamantane, 1 mmole of NHPI and 0.005 mmole of Co(AA)2 and the mixture was stirred for 6 hours at 75° C. As a result,the conversion was 76% and 1,3,5-tricarboxy-7-adamantanol was obtained in a 70% yield.

Sources & evidence

ORD record
ord-51b9795fe03443eaaaf389cd159500b2
Source dataset
uspto-grants-2002_05
Patent number
US06392104B1

Reaction notes

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