HCID 11827930, compound → HCID 86758094, compound

Participants

Reaction Conditions

Reaction Steps

Potassium bis(tris(pentafluorophenyl)borane)azide (1500.0 mg, 1.3573 mmol) and dioctadecylmethylammonium chloride (777.0 mg, 1.3573 mmol) were placed in a 50 mL flask. The solids were cooled to −78° C. and taken up in 20 mL of dichloromethane, added via syringe under argon counter-flow. As the stirred mixture warmed, the original solids dissolved and a fine precipitate of a colorless solid formed. The solid was removed by filtration and washed with two 5 mL portions of dichloromethane. The filtrate stripped under high vacuum, giving a colorless oil. Yield, 1646 mg, 75.33 percent.

Provenance & Evidence