HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 54358329, compound → HCID 54316182, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 54358329 | HCID 54358329 | — |
| Catalyst | HCID 86736741 | HCID 86736741 | — |
| Solvent | Ethyl Acetate | HCID 8857 | — |
| Product | HCID 54316182 | HCID 54316182 | — |
Reaction Steps
1.0 g. of the 7-allyl-enone 72, 5 ml. EtOAc and 50 mg. triphenylphosphine rhodium chloride (Wilkinson's catalyst) were allowed to stir two hours (under H2 atmosphere). The reaction products were filtered through 25 ml. silica gel, and evaporated to dryness to yield fairly pure title product, 76, as confirmed by proton NMR.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05693809 |
| Source dataset | uspto-grants-1997_12 |
| ORD ID | ord-280cac7b44ac44bb8c744f4610ac38bc |
| Source note | uspto-grants-1997_12 |