HuagongsheHuagongshe Chemistry Print Report · For research reference only
n-Hydroxy-1,1-bis(4-methoxyphenyl)methanimine → 4,4'-Dimethoxybenzhydrylamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | n-Hydroxy-1,1-bis(4-methoxyphenyl)methanimine | HCID 289718 | — |
| Reactant | Ammonium Acetate | HCID 517165 | — |
| Reactant | Sodium cyanoborohydride | HCID 5003444 | — |
| Catalyst | titanium(III) trichloride | HCID 10313229 | — |
| Product | 4,4'-Dimethoxybenzhydrylamine | HCID 350042 | 80.8% |
Reaction Steps
Following a procedure similar to that described in Preparation 12, but using 10.7 g of 4,4'-dimethoxybenzophenone oxime, 33.9 g of ammonium acetate, 7.46 g of sodium cyanoborohydride, and 79 ml of a 17-19% by volume aqueous solution of titanium trichloride, 8.18 g of the title compound were obtained, as an oily substance.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05698720 |
| Source dataset | uspto-grants-1997_12 |
| ORD ID | ord-5c48a2fb78ef4e1680d2880fe6c4d5e0 |
| Source note | uspto-grants-1997_12 |