HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzyl 4-methoxycarbonylmethyloxyphenylacetate → 4-(2-Methoxy-2-oxoethoxy)-benzeneacetic acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzyl 4-methoxycarbonylmethyloxyphenylacetate | HCID 53972878 | — |
| Catalyst | Palladium hydroxide | HCID 9942167 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | 4-(2-Methoxy-2-oxoethoxy)-benzeneacetic acid | HCID 54523793 | — |
Reaction Steps
7.8 g (0.025 Mol) of benzyl 4-methoxycarbonylmethyloxyphenylacetate are exhaustively hydrogenated in 150 ml of methanol in the presence of 8 g of palladium hydroxide on charcoal at ambient temperature and under a hydrogen pressure of 50 psi. After the removal of the catalyst the mother liquor is evaporated to dryness under reduced pressure.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05700801 |
| Source dataset | uspto-grants-1997_12 |
| ORD ID | ord-5fcc763078524a03a5cb5d94f7393cdd |
| Source note | uspto-grants-1997_12 |