Methylenechloride Hexane → HCID 21459577, compound

Participants

Reaction Steps

3.1 g (8.5 mmol) of the diol obtained in Example 10, in solution in 60 ml of CH2Cl2, were treated with 5.5 g of pyridinium chlorochromate. The reaction mixture was maintained under stirring at room temperature for 3 hours. The reaction mixture was then filtered through Celite. The organic phase was washed with a saturated ammonium chloride solution, rinsed with water, dried and evaporated to yield, after chromatography on silica in a CH2Cl2 /hexane (9/1) eluent mixture, 2 g (66%) of the expected compound, melting at 138°-142° C.

Provenance & Evidence