HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethyl Sulfide → 1-Benzoyl-2,3-diphenylcyclopropane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethyl Sulfide | HCID 1068 | — |
| Reactant | Cinnamoylbenzene | HCID 7189 | — |
| Product | 1-Benzoyl-2,3-diphenylcyclopropane | HCID 10957493 | — |
Reaction Steps
The same method was applied for the cyclopropanation of chalcone using a stoichiometric amount of dimethyl sulphide (36.5 μl; 0.5 mmol). Column chromatography over silica afforded the title compound as a 5:1 mixture of trans; cis cyclopropanes as a yellowy solid (54 mg; 36.2%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05703246 |
| Source dataset | uspto-grants-1997_12 |
| ORD ID | ord-9e8016f61a0e4985a3fb7f2c971d9d9a |
| Source note | uspto-grants-1997_12 |