HCID 15788050, compound → HCID 21461385, compound

HRID 1941525Notes

Reaction equation

HRID 1941525 reaction equation
C=C1OCC2C(OC(C)(C)O2)CO1.Br[CH2:15][CH:16]1[O:25][CH2:24][CH:23]2[CH:19]([O:20][CH:21]([CH2:26][CH3:27])[O:22]2)[CH2:18][O:17]1>>[CH2:15]=[C:16]1[O:17][CH2:18][CH:19]2[CH:23]([O:22][CH:21]([CH2:26][CH3:27])[O:20]2)[CH2:24][O:25]1

Participants

3

Reactant 2

HCID 15788050HCID 15788050, compoundHCID 70344473HCID 70344473, compound

Product 1

HCID 21461385HCID 21461385, compoundYield 51%

Procedure

4-Methylene-9 -ethyl-3,5,8, 10-tetraoxabicyclo [5.3.0]decane was prepared in a similar way to 4-methylene-9,9-di methyl-3,5,8, 10-tetraoxabicyclo[5.3.0]decane starting from 131 mmol (35 g) of 4-bromomethyl-9-ethyl-3,5,8, 10-tetraoxabicyclo[5.3.0]decane, fractional distillation from 65° to 68° C. (0.3 mbar) giving 12.5 g (51% yield).

Workup

  1. customgiving 12.5 g (51% yield)

Sources & evidence

ORD record
ord-23f6221a08f24ee5afa32e1f1d313b6b
Source dataset
uspto-grants-1997_12
Patent number
US05703249

Reaction notes

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