HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzaldehyde → HCID 21461383, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzaldehyde | HCID 240 | — |
| Reactant | 2-Methylbenzenesulfonic acid | HCID 6925 | — |
| Reactant | HCID 21461382 | HCID 21461382 | — |
| Reactant | HCID 21461387 | HCID 21461387 | — |
| Solvent | Chloroform | HCID 6212 | — |
| Product | HCID 21461383 | HCID 21461383 | — |
Reaction Steps
4-Bromomethyl-9-phenyl-3,5,8,10-tetraoxabicyclo[5.3.0]decane was prepared in a similar way to 4-bromomethyl-9,9-dimethyl-3,5,8, 10-tetraoxabicyclo[5.3.0]decane from 64.7 g of 2-bromomethyl-5,6-dihydroxy- 1,3-dioxepane (285 mmol) and 187.0 g of benzaldehyde (1760 mmol) in chloroform. The reaction time was 8 days, a fresh spatula tip of toluenesulphonic acid being added every day.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05703249 |
| Source dataset | uspto-grants-1997_12 |
| ORD ID | ord-e37bb5e536a641fba0d30485626860ce |
| Source note | uspto-grants-1997_12 |