HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dithioerythritol → 6-Deoxyallitol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dithioerythritol | HCID 439352 | — |
| Reactant | (3R,4S,5S)-3,4,5,6-tetrahydroxyhexan-2-one | HCID 22820975 | — |
| Reactant | Deoxyhexulose | HCID 86641207 | — |
| Product | 6-Deoxyallitol | HCID 125280 | — |
Reaction Steps
1-Deoxy L-psicose prepared via a reaction of 1-deoxy L-fructose with DTE was reduced to obtain 1-deoxy L-allitol, which was then oxidized microbially (IK7), to produce 6-deoxy D-psicose. 1-Deoxy D-psicose thus obtained reacted with DTE. The reaction conditions are as follows.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08389248B2 |
| Source dataset | uspto-grants-2013_03 |
| ORD ID | ord-0e361772d189481b8e0b4651e20f9776 |
| Source note | uspto-grants-2013_03 |