D-Arabinose → L-Fuculose

HRID 1941746Notes

Reaction equation

[O:1]=[CH:2][C@H:3]([C@@H:5]([C@@H:7]([C@H:9]([CH3:11])[OH:10])[OH:8])[OH:6])[OH:4].O=C[C@H]([C@@H]([C@@H](CO)O)O)O>>[OH:1][CH2:2][C:3]([C@@H:5]([C@@H:7]([C@H:9]([CH3:11])[OH:10])[OH:8])[OH:6])=[O:4]

Participants

Reactant 2

HCID 66308D-Arabinose

HCID 3034656L-(-)-Fucose

Product 1

HCID 6857362L-Fuculose

Procedure

Under the following reaction conditions, L-fucose (6-deoxy L-galactose) was isomerized with D-arabinose isomerase, to produce 6-deoxy L-tagatose.

Sources & evidence

ORD record: ord-551c875aeee54e19a50fd7e5753ee54d
Source dataset: uspto-grants-2013_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08389248B2

Reaction notes

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