Aluminum nitrate → Decanedioic acid, aluminum salt (3:2)

HRID 1942826Notes

Reaction equation

[N+]([O-])([O-])=O.[Al+3:5].[N+]([O-])([O-])=O.[N+]([O-])([O-])=O.[C:14]([O-:27])(=[O:26])[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][C:23]([O-:25])=[O:24].[Na+].[Na+].[Al]>>[C:14]([O-:27])(=[O:26])[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][C:23]([O-:25])=[O:24].[Al+3:5].[C:14]([O-:27])(=[O:26])[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][C:23]([O-:25])=[O:24].[C:14]([O-:27])(=[O:26])[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][C:23]([O-:25])=[O:24].[Al+3:5]

Participants

Reactant 3

HCID 26053Aluminum nitrate

HCID 134734Decanedioic acid, sodium salt (1:2)3×

HCID 5359268Aluminum

Product 1

HCID 79641Decanedioic acid, aluminum salt (3:2)

Procedure

An aluminum sebacate soap (aluminum sebacate soap (II)) is synthesized in the same manner as that described in the item (1) except that a 5% aqueous solution of aluminum nitrate corresponding to a half amount of that described above, that is, 1.025 moles with respect to 1 mole of sodium sebacate is added to the aqueous solution of sodium sebacate. It should be noted that the concentration of sodium sebacate is adjusted in such a manner that the theoretical aluminum soap concentration is 1%.

Sources & evidence

ORD record: ord-c8569689b0814512884d9d67c52299e5
Source dataset: uspto-grants-2013_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08389620B2

Reaction notes

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