4-Nitrophenethyl alcohol → 1-[2-[(6-Bromohexyl)oxy]ethyl]-4-nitrobenzene

HRID 1944880Notes

Reaction equation

HRID 1944880 reaction equation
[Br:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7]OCCCCC1C=CC([N+]([O-])=O)=CC=1.[N+:22]([C:25]1[CH:30]=[CH:29][C:28]([CH2:31][CH2:32][OH:33])=[CH:27][CH:26]=1)([O-:24])=[O:23]>>[Br:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][O:33][CH2:32][CH2:31][C:28]1[CH:27]=[CH:26][C:25]([N+:22]([O-:24])=[O:23])=[CH:30][CH:29]=1

Participants

3

Reactant 2

HCID 74944-Nitrophenethyl alcoholHCID 200714241-(4-((6-Bromohexyl)oxy)butyl)-4-nitrobenzene

Product 1

HCID 135927841-[2-[(6-Bromohexyl)oxy]ethyl]-4-nitrobenzene

Procedure

The title compound was synthesized in a manner analogous to that described for Intermediate 52, using 2-(4-nitrophenyl)ethanol in place of 4-(4-nitrophenyl)butan-1-ol. ES/MS calcd. for C14H21BrNO3+ 330.1. Found m/z=330.1 (M+H)+.

Sources & evidence

ORD record
ord-ad1657968d1844349d8dc76372b4a078
Source dataset
uspto-grants-2013_03
Patent number
US08394829B2

Reaction notes

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