HRID1944908

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：[N-]=[N+]=NC[C@H](O)c1ccc(OCc2ccccc2)c2[nH]c(=O)ccc12

HCID58505170

未命名化合物

结构：COc1cccc(Nc2c(C(N)=O)cnc3c(C)cc(S(=O)(=O)c4cccc(C(=O)N5CCC(OCCCCCCO[Si](C)(C)C(C)(C)C)CC5)c4)cc23)c1

HCID66988582

未命名化合物

PRODUCTS

生成物

结构：COc1cccc(Nc2c(C(N)=O)cnc3c(C)cc(S(=O)(=O)c4cccc(C(=O)N5CCC(OCCCCCCO)CC5)c4)cc23)c1

HCID66988385

未命名化合物

PROCEDURE

实验过程

The title compound was synthesized in a manner analogous to that described for Intermediate 5, using Intermediate 84 as a substrate. ES/MS calcd. for C36H43N4O7S+ 675.3. Found m/z=675.2 (M+H)+.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-91fc730579554fcea875917d70a38f28
来源数据集: uspto-grants-2013_03
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08394829B2
来源说明: uspto-grants-2013_03

反应 SMILES

N(C[C@@H](C1C=CC(OCC2C=CC=CC=2)=C2C=1C=CC(=O)N2)O)=[N+]=[N-].[Si]([O:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][O:40][CH:41]1[CH2:46][CH2:45][N:44]([C:47]([C:49]2[CH:50]=[C:51]([S:55]([C:58]3[CH:59]=[C:60]4[C:65](=[C:66]([CH3:68])[CH:67]=3)[N:64]=[CH:63][C:62]([C:69]([NH2:71])=[O:70])=[C:61]4[NH:72][C:73]3[CH:78]=[CH:77][CH:76]=[C:75]([O:79][CH3:80])[CH:74]=3)(=[O:57])=[O:56])[CH:52]=[CH:53][CH:54]=2)=[O:48])[CH2:43][CH2:42]1)(C(C)(C)C)(C)C>>[OH:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][O:40][CH:41]1[CH2:46][CH2:45][N:44]([C:47]([C:49]2[CH:50]=[C:51]([S:55]([C:58]3[CH:59]=[C:60]4[C:65](=[C:66]([CH3:68])[CH:67]=3)[N:64]=[CH:63][C:62]([C:69]([NH2:71])=[O:70])=[C:61]4[NH:72][C:73]3[CH:78]=[CH:77][CH:76]=[C:75]([O:79][CH3:80])[CH:74]=3)(=[O:57])=[O:56])[CH:52]=[CH:53][CH:54]=2)=[O:48])[CH2:43][CH2:42]1