HRID1944909

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：[N-]=[N+]=NC[C@H](O)c1ccc(OCc2ccccc2)c2[nH]c(=O)ccc12

HCID58505170

未命名化合物

结构：COc1cccc(Nc2c(C(N)=O)cnc3c(C)cc(S(=O)(=O)c4cccc(C(=O)N5CCN(CCCCCCO[Si](C)(C)C(C)(C)C)CC5)c4)cc23)c1

HCID66988288

未命名化合物

PRODUCTS

生成物

结构：COc1cccc(Nc2c(C(N)=O)cnc3c(C)cc(S(=O)(=O)c4cccc(C(=O)N5CCN(CCCCCCO)CC5)c4)cc23)c1

HCID66988062

未命名化合物

PROCEDURE

实验过程

The title compound was synthesized in a manner analogous to that described for Intermediate 5, using Intermediate 85 as a substrate. ES/MS calcd. for C35H42N5O6S+ 660.3. Found m/z=660.3 (M+H)+.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-daa0afe350214c97aa6a2d3bc9f9a80d
来源数据集: uspto-grants-2013_03
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08394829B2
来源说明: uspto-grants-2013_03

反应 SMILES

N(C[C@@H](C1C=CC(OCC2C=CC=CC=2)=C2C=1C=CC(=O)N2)O)=[N+]=[N-].[Si]([O:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][N:40]1[CH2:45][CH2:44][N:43]([C:46]([C:48]2[CH:49]=[C:50]([S:54]([C:57]3[CH:58]=[C:59]4[C:64](=[C:65]([CH3:67])[CH:66]=3)[N:63]=[CH:62][C:61]([C:68]([NH2:70])=[O:69])=[C:60]4[NH:71][C:72]3[CH:77]=[CH:76][CH:75]=[C:74]([O:78][CH3:79])[CH:73]=3)(=[O:56])=[O:55])[CH:51]=[CH:52][CH:53]=2)=[O:47])[CH2:42][CH2:41]1)(C(C)(C)C)(C)C>>[OH:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][N:40]1[CH2:41][CH2:42][N:43]([C:46]([C:48]2[CH:49]=[C:50]([S:54]([C:57]3[CH:58]=[C:59]4[C:64](=[C:65]([CH3:67])[CH:66]=3)[N:63]=[CH:62][C:61]([C:68]([NH2:70])=[O:69])=[C:60]4[NH:71][C:72]3[CH:77]=[CH:76][CH:75]=[C:74]([O:78][CH3:79])[CH:73]=3)(=[O:56])=[O:55])[CH:51]=[CH:52][CH:53]=2)=[O:47])[CH2:44][CH2:45]1