Methanol → 1,18-Dimethyl-9-octadecenedicarboxylic acid
Reaction equation
[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][C:11]([O:13]C)=[O:12].[O:15]1CC[O:17][CH2:16]1.O=[CH:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29]CC(OC)=O.[CH3:35]O>>[CH3:35][C:10]([C:11]([OH:13])=[O:12])([C:16]([OH:15])=[O:17])[CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH:2]=[CH:1][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29]Participants
4
Procedure
Methyl 11-undecanoate-[1,3]dioxolane (the cyclic acetal of methyl 11-oxoundecanoate): MS (ESI-positive, CH3OH, m/z): 281.2 (MNa+, calc. 281.4).
Sources & evidence
- ORD record
- ord-928402114a8b4493b9dbced1f7e6b45e
- Source dataset
- uspto-grants-2013_03
- Patent number
- US08394996B2
Reaction notes
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