HCID 13677845, compound → HCID 76610493, compound

HRID 1948369Notes

Reaction equation

HRID 1948369 reaction equation
[N:1]([CH:4]1[CH2:9][CH2:8][N:7]([C:10]([O:12][CH2:13][CH3:14])=[O:11])[CH2:6][CH:5]1[OH:15])=[N+:2]=[N-:3].BrC1CCN(C(OCC)=O)CC1O[Si:29]([C:32]([CH3:35])([CH3:34])[CH3:33])([CH3:31])[CH3:30]>>[N:1]([CH:4]1[CH2:9][CH2:8][N:7]([C:10]([O:12][CH2:13][CH3:14])=[O:11])[CH2:6][CH:5]1[O:15][Si:29]([C:32]([CH3:35])([CH3:34])[CH3:33])([CH3:31])[CH3:30])=[N+:2]=[N-:3]

Participants

3

Reactant 2

HCID 13677845HCID 13677845, compoundHCID 68519870HCID 68519870, compound2×

Product 1

HCID 76610493HCID 76610493, compound

Procedure

The title compound was prepared in a manner analogous to (Intermediate 238) starting with ethyl 4-bromo-3-{[tert-butyl(dimethyl)silyl]oxy}piperidine-1-carboxylate (Intermediate 241). MS (GC-EI)[(M-N2)+]: 300 for C14H28N4O3Si.

Sources & evidence

ORD record
ord-ff02a4f1dcaf4cad9577dd4e48649d60
Source dataset
uspto-grants-2013_03
Patent number
US08399489B2

Reaction notes

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