HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Bromide → 3-Bromoimidazo[1,2-a]pyridine-8-carbaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Bromide | HCID 253877 | — |
| Reactant | Imidazo(1,2-a)pyridine-8-carbaldehyde | HCID 10997174 | — |
| Product | 3-Bromoimidazo[1,2-a]pyridine-8-carbaldehyde | HCID 46206057 | — |
Reaction Steps
From 4a (yield: 35%); mp 104-106° C.; IR (KBr) 1694, 1186 cm−1; 1H NMR (400 MHz, CDCl3) δ 7.09 (t, 1H J=7 Hz), 7.74 (s, 1H), 7.86 (d, 1H, J=7 Hz), 8.32 (d, 1H, J=7 Hz), 10.66 (s, 1H); 13C NMR (100 MHz, CDCl3) δ 96.4, 112.9, 124.2, 127.1, 128.5, 134.6, 144.2, 188.2; MS m/z 226 (M++2, 45), 224 (M+, 46), 198 (99), 196 (100), 117 (76), 90 (54), 63 (30).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08404707B2 |
| Source dataset | uspto-grants-2013_03 |
| ORD ID | ord-30dbd52d43504c6c8135ce101a531ee4 |
| Source note | uspto-grants-2013_03 |