Triethyl phosphite → HCID 87511314, compound

HRID 1951966Notes

Reaction equation

HRID 1951966 reaction equation
[C:1]([O:4][CH2:5][CH:6](Cl)[O:7][CH2:8][CH3:9])(=[O:3])[CH3:2].[CH2:11]([O:13][P:14]([O:18]CC)[O:15][CH2:16][CH3:17])[CH3:12].C(OCC(P(OCC)(OCC)=O)OCC)(=O)C>>[C:1]([O:4][CH:5]([P:14]([O:15][CH2:16][CH3:17])([O:13][CH2:11][CH3:12])=[O:18])[CH2:6][O:7][CH2:8][CH3:9])(=[O:3])[CH3:2]

Participants

4

Reactant 3

HCID 31215Triethyl phosphiteHCID 86642399HCID 86642399, compoundHCID 87511316HCID 87511316, compound

Product 1

HCID 87511314HCID 87511314, compound

Conditions

Temperature
150 °C

Procedure

18.5 g (112 mmol) of chloro-ethoxy-ethyl acetate and 19.2 ml (112 mmol) of triethylphosphite are put in a flask and heated at 150° C. for 5 hours. The progress of the reaction is monitored with NMR. 34 g (100%) of (diethoxy-phosphoryl)-ethoxy-ethyl acetate is obtained directly in the form of a colorless liquid.

Workup

  1. customis obtained directly in the form of a colorless liquid

Sources & evidence

ORD record
ord-08586fb13d4f43f28b1f79ceaccb79ab
Source dataset
uspto-grants-2013_03
Patent number
US08404836B2

Reaction notes

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