HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethyl phosphite → HCID 15272444, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethyl phosphite | HCID 31215 | — |
| Reactant | 1-[Bromo(difluoro)methyl]-2,3,4,5,6-pentafluorobenzene | HCID 21864277 | — |
| Solvent | 1,4-Dioxane | HCID 31275 | — |
| Product | HCID 15272444 | HCID 15272444 | 96% |
Reaction Steps
Perfluorobenzyl bromide (2.00 g, 7.66 mmol) and P(OEt)3 (1.66 g, 9.96 mmol) were dissolved in 1,4-dioxane (10 ml) and heated at reflux for 14 hours. Fractional distillation (66-78° C., 60 mm Hg) afforded the product as a colorless oil (2.43 g, 96%)
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08405069B2 |
| Source dataset | uspto-grants-2013_03 |
| ORD ID | ord-e0e4836cc265494fa478fbe0610d056e |
| Source note | uspto-grants-2013_03 |