1-Iodohexane → HCID 23300528, compound

HRID 1952826Notes

Reaction equation

[N+:1]([C:4]1[CH:13]=[C:12]2[C:7]([C:8]([OH:23])=[C:9]([O:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[C:10](=[O:15])[N:11]2[CH3:14])=[CH:6][CH:5]=1)([O-:3])=[O:2].[CH2:24](I)[CH2:25][CH2:26][CH2:27]CC>>[N+:1]([C:4]1[CH:13]=[C:12]2[C:7]([C:8]([O:23][CH2:24][CH2:25][CH2:26][CH3:27])=[C:9]([O:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[C:10](=[O:15])[N:11]2[CH3:14])=[CH:6][CH:5]=1)([O-:3])=[O:2]

Participants

Reactant 2

HCID 125271-Iodohexane

HCID 54713995HCID 54713995, compound

Product 1

HCID 23300528HCID 23300528, compoundYield 57%

Procedure

In accordance with EXAMPLE 2, using 7-nitro-3-hexyloxy-4-hydroxy-1-methyl-2(1H)-quinolinone, hexyl iodide was used instead of methyl iodide, 7-nitro-4-butoxy-3-hexyloxy-1-methyl-2(1H)-quinolinone was provided. Then in accordance with EXAMPLE 3, the title compound (51) was obtained by reduction reaction of nitro group. (yield=57%)

Sources & evidence

ORD record: ord-983b65995cd64d51a10f09474d3ef13f
Source dataset: uspto-grants-2000_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06114352

Reaction notes

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