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HRID1953392

反应详情

EQUATION

反应方程式

HRID 1953392 的结构方程式

REACTANTS

反应物

4
结构：CC(C)[C@H](N)C(=O)OC(C)(C)C
HCID114626

tert-Butyl valinate

C9H19NO2

结构：CC(C)[C@@H](N)C(=O)OC(C)(C)C
HCID6931638

tert-butyl D-valinate

C9H19NO2

结构：O=S(=O)(Cl)c1ccc2c(c1)Sc1ccccc1S2
HCID15487617

未命名化合物

结构：O=S(=O)(Cl)c1ccc2c(c1)Sc1ccccc1O2
HCID15487618

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)[C@H](NS(=O)(=O)c1ccc2c(c1)Sc1ccccc1O2)C(=O)O
HCID15487607

未命名化合物

PROCEDURE

实验过程

When in the procedure of Example 1, Step (b), thianthrene-2-sulfonyl chloride is replaced by phenoxathiine-2-sulfonyl chloride and (L)-valine-t-butyl ester is replaced with (D)-valine-t-butyl ester, (S)-3-methyl-2-(phenoxathiine-2-sulfonylamino)-butyric acid is obtained as an off-white solid; mp 171-175° C.