Benzylamine → HCID 22252169, compound

Participants

Reaction Steps

This product was prepared by stirring a solution of Example 31 (0.2 g, 0.43 mmol) in 50 mL of THF with benzylamine (0.5 mL, 9 equiv.), Et3N (1 mL) and diphenylphosphoryl azide (0.5 mL). After two days the reaction mixture was concentrated in vacuo. The residue was taken up in 100 mL of DCM and washed with 3×50 mL of water. Drying over Na2SO4 and evaporation of the solvent gave a residue which was purified via flash chromatography with cyclohexane and Et2O. Evaporation in vacuo and recrystallization from EtOH gave the title compound (0.03 g, 13%) as white crystals.

Provenance & Evidence