Methacrylic Acid → 2-Methylidene-5-phenylpent-4-enoic acid

HRID 1953638Notes

Reaction equation

HRID 1953638 reaction equation
[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[C:9]([OH:14])(=[O:13])[C:10]([CH3:12])=[CH2:11].C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C1C=CC=CC=1>[CH:1]([CH2:12][C:10](=[CH2:11])[C:9]([OH:14])=[O:13])=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

Participants

5

Reactant 3

HCID 4093Methacrylic AcidHCID 7187Benzoyl PeroxideHCID 7501Styrene

Product 1

HCID 539699792-Methylidene-5-phenylpent-4-enoic acid

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

First, 100 g of styrene, 0.033 g of methacrylic acid, and 0.5 g of BPO (benzoyl peroxide) were dissolved in benzene (solvent), and the resulting solution was kept at 80° C. for 3 hours. Then, benzene as solvent was removed, and the styrene-methacrylic acid copolymer was obtained. This copolymer is hereinafter referred to as SMCPa. The content of methacrylic acid as a functional monomer in SMCPa was 0.05 mol %.

Workup

  1. customThen, benzene as solvent was removed

Sources & evidence

ORD record
ord-703fed507a764fae9e5c2414e53b9ce8
Source dataset
uspto-grants-2000_09
Patent number
US06117932

Reaction notes

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