HCID 13923039, compound → HCID 23296707, compound

HRID 1954347Notes

Reaction equation

HRID 1954347 reaction equation
[NH2:1][C:2]1[C:11]([C:12]([O:14][CH2:15][CH3:16])=[O:13])=[C:10]2[C:4](=[CH:5][CH:6]=[C:7]([CH2:17][C:18]([OH:20])=O)[CH:8]=[CH:9]2)[C:3]=1[C:21]([O:23][CH2:24][CH3:25])=[O:22].C([O:28][P:29]([CH2:34][O:35][NH2:36])([O:31]CC)=[O:30])C>>[NH2:1][C:2]1[C:11]([C:12]([O:14][CH2:15][CH3:16])=[O:13])=[C:10]2[C:4](=[CH:5][CH:6]=[C:7]([CH2:17][C:18](=[O:20])[NH:36][O:35][CH2:34][P:29]([OH:31])([OH:30])=[O:28])[CH:8]=[CH:9]2)[C:3]=1[C:21]([O:23][CH2:24][CH3:25])=[O:22]

Participants

3

Reactant 2

HCID 13923039HCID 13923039, compoundHCID 15391985HCID 15391985, compound

Product 1

HCID 23296707HCID 23296707, compound

Procedure

In an analogous manner to that described in Example 26, from diethyl 2-amino-6-carboxymethyl-azulene-1,3-dicarboxylate and phosphonomethoxyamine (L. Maier, Phosphorus, Sulfur, and Silicon 1993, Vol. 76, 119-122) the title compound is obtained as an amorphous powder.

Sources & evidence

ORD record
ord-3d5db85efa8e4da1a96fef5176cc0b1d
Source dataset
uspto-grants-2000_09
Patent number
US06121322

Reaction notes

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