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HRID1954461

反应详情

EQUATION

反应方程式

HRID 1954461 的结构方程式

REACTANTS

反应物

5
结构：O=[N+]([O-])O
HCID944

Nitric Acid

HNO3

结构：CC(=O)OC(C)=O
HCID7918

Acetic anhydride

C4H6O3

结构：CCOCC.FB(F)F
HCID8000

Ethane, 1,1'-oxybis-, compd. with trifluoroborane (1:1)

C4H10BF3O

结构：O=[N+]([O-])C1([N+](=O)[O-])CNC1
HCID5231706

3,3-dinitroazetidine

C3H5N3O4

结构：CC(C)(C)N1CC([N+](=O)[O-])([N+](=O)[O-])C1
HCID10954639

tert-butyl-3,3-dinitroazetidine

C7H13N3O4

PRODUCTS

生成物

1
结构：O=[N+]([O-])N1CC([N+](=O)[O-])([N+](=O)[O-])C1
HCID9794126

1,3,3-Trinitroazetidine

C3H4N4O6

收率 90%

PROCEDURE

实验过程

The upper reaction scheme is the conversion of the N-tertiarybutyl,3,3 dinitroazetidine to the N-acetyl, 3,3 dinitroazetidine. The reaction conditions are a catalytic amount of boron trifluoride etherate as the Lewis acid and acetic anhydride as the solvent-reactant. The temperature is 125 degrees C. As shown there was about a 90% yield. The compound is nitrated with 70% nitric acid and heated to give TNAZ.

WORKUP

后处理

  1. customThe upper reaction scheme
  2. customThe reaction conditions
  3. customis 125 degrees C
  4. temperatureheated