1-Chloro-4-acetoxynonane → HCID 22615362, compound

HRID 1955015Notes

Reaction equation

HRID 1955015 reaction equation
C[O:2][C:3](=[O:18])[CH2:4][O:5][C:6]1[CH:11]=[CH:10][CH:9]=[C:8]([CH2:12][NH:13][S:14]([CH3:17])(=[O:16])=[O:15])[CH:7]=1.Cl[CH2:20][CH2:21][CH2:22][CH:23]([O:29]C(=O)C)[CH2:24][CH2:25][CH2:26][CH2:27][CH3:28]>>[OH:29][CH:23]([CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])[CH2:22][CH2:21][CH2:20][N:13]([CH2:12][C:8]1[CH:7]=[C:6]([CH:11]=[CH:10][CH:9]=1)[O:5][CH2:4][C:3]([OH:2])=[O:18])[S:14]([CH3:17])(=[O:16])=[O:15]

Participants

3

Reactant 2

HCID 131047161-Chloro-4-acetoxynonaneHCID 54471702HCID 54471702, compound

Product 1

HCID 22615362HCID 22615362, compound

Procedure

The title compound was prepared from [3-(methanesulfonylamino-methyl)phenoxy]-acetic acid methyl ester (Preparation 10) and acetic acid 1-(3-chloropropyl)-hexyl ester using the alkylation procedure described in U.S. Pat. No. 4,033,996. 1H NMR (CDCl3) δ 7.31-7.26 (m, 1 H), 7.02-6.84 (m, 3H), 4.68 (s, 2H), 4.35 (s, 2H), 3.91-3.89 (m, 1 H), 3.20-3.12 (m, 2H), 2.83 (s, 3H), 1.94-1.92 (m, 1H), 1.79-1.24 (m, 12H), 0.87 (t, 3H); MS 400 (M+ -1).

Sources & evidence

ORD record
ord-627531c649944d849f4a4e2caa7b73e8
Source dataset
uspto-grants-2000_09
Patent number
US06124314

Reaction notes

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