Water → Vinylidene fluoride

HRID 1955489Notes

Reaction equation

HRID 1955489 reaction equation
[C:1]([F:4])([F:3])=[CH2:2].[C:5]([O:12][CH3:13])(=[O:11])/[CH:6]=[CH:7]\[C:8]([O-:10])=[O:9].[OH2:14]>>[C:5]([O:11][O:12][C:5]([O:11][CH:1]([CH3:2])[CH3:2])=[O:14])([O:12][CH:13]([CH3:1])[CH3:13])=[O:14].[C:1]([F:4])([F:3])=[CH2:2].[C:5]([O:12][CH3:13])(=[O:11])/[CH:6]=[CH:7]\[C:8]([O-:10])=[O:9]

Participants

5

Reactant 2

HCID 962WaterHCID 86752396HCID 86752396, compound

Product 3

HCID 6369Vinylidene fluorideHCID 7769Diisopropyl peroxydicarbonateHCID 21768182Mono-methyl maleate

Procedure

In a 2 liter-autoclave, 1040 g of deionized water, 0.8 g of methyl cellulose, 2 g of diisopropyl peroxydicarbonate (IPP), 396 g of vinylidene fluoride and 4 g of monomethyl maleate (giving a vinylidene fluoride/monomethyl maleate (mol ratio)=100/1.01) were charged and subjected to suspension polymerization at 28° C.

Sources & evidence

ORD record
ord-98056ee2a51c49eda097a1555ca8312f
Source dataset
uspto-grants-1998_07
Patent number
US05776637

Reaction notes

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