HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1955741Generated: October 30, 2026
Tetrabutylammonium permanganate → HCID 19072548, compound
https://huagongshe.com/reaction/1955741
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Tetrabutylammonium permanganate | HCID 11760202 | — |
| Reactant | N-4-Tolylsulphonyl-2-[4-(2-butyl-4-chloro-5-formyl-imidazol-1-yl-methyl)-phenyl]-2-cyclopentyl-acetamide | HCID 19072485 | — |
| Solvent | Pyridine | HCID 1049 | — |
| Product | HCID 19072548 | HCID 19072548 | — |
Reaction Steps
250 mg (0.45 mmol) of the compound from Example III are dissolved in 2.5 ml (0.45 mmol) of pyridine and 162 mg of tetrabutylammonium permanganate, dissolved in 1.5 ml of pyridine, are added at 60° C., and the mixture is stirred at 60° C. for 2 h. The pyridine is evaporated, and the residue is taken up in water, acidified with dilute HCl and extracted with ethyl acetate. The organic phase is concentrated and the residue is chromatographed on silica gel 60 using CH2Cl2 /MeOH (10:1).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US05776964 |
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| Source dataset | uspto-grants-1998_07 |
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| ORD ID | ord-f55a8a9747e94994b369373934dccc4c |
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| Source note | uspto-grants-1998_07 |
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