HCID 54512044, compound → 1-Propanol, 3,3,3-trifluoro-, 1-acetate

Participants

Reaction Steps

3,3,3-Trifluoropropenyl acetate (7.1. g) was hydrogenated in a glass pressure bottle overnight at 65°-70° C. using 0.1 g 10% Pd/C as catalyst and a maximum H2 pressure of 35 psi. The catalyst was separated by centrifugation, providing 6.7 g of 97% pure CF3CH2CH2OAc (93% yield). Bp 112°-113° C. [lit. 112° C.; B. T. Golding, P. J. Sellars, and W. P. Watson, J. Fluorine Chem., 30 (1985) 153]. 1H NMR: δ4.29 (t, 2 H, J=6.4 Hz), 2.4 (m, 2 H), 2.07 (s, 3H). 19F NMR: δ-65.8 (t, J=10.4 Hz).

Provenance & Evidence