HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phosphonium → HCID 19073609, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phosphonium | HCID 5460504 | — |
| Reactant | HCID 19073578 | HCID 19073578 | — |
| Reactant | HCID 19073648 | HCID 19073648 | — |
| Reactant | Tert-butyl 2-(3,4-dichlorobenzyl)acetoacetate | HCID 19073669 | — |
| Reactant | HCID 19073695 | HCID 19073695 | — |
| Reactant | HCID 19073702 | HCID 19073702 | — |
| Reactant | HCID 19073705 | HCID 19073705 | — |
| Reactant | Phosphonium, (2-naphthalenylmethyl)triphenyl-, chloride | HCID 21904192 | — |
| Product | HCID 19073609 | HCID 19073609 | — |
Reaction Steps
The following compounds were prepared in the same manner as in Example 123 except that tert-butyl 2-(3,4-dichlorobenzyl)acetoacetate and/or (2-naphthylmethyl)triphenylphosphonium chloride used as the starting materials in the above reaction were changed to the respective tert-butyl 2-(4-chlorobenzyl)acetoacetate and/or corresponding phosphonium derivatives: (1RS,2RS,3E)-4-(2-benzo[b]furanyl)-2-(3,4-dichlorobenzyl)-1-methyl-3-butenylamine, (1RS,2RS,3E)-2-(3,4-dichlorobenzyl)-1-methyl-4-{3-(3-thienyl)phenyl}-3-butenylamine, (1RS,2RS,3E)-2-(3,4-dichlorobenzyl)-1-methyl-4-(1-naphthyl)-3-butenylamine and (1RS,2RS,3E)-2-(4-chlorobenzyl)-4-(4-chlorophenyl)-1-methyl-3-butenylamine.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05777150 |
| Source dataset | uspto-grants-1998_07 |
| ORD ID | ord-c530a07d408a4690b0c3c9c0a4f180ae |
| Source note | uspto-grants-1998_07 |