Chlorotrifluoroethylene → HCID 18663612, compound

HRID 1956581Notes

Reaction equation

HRID 1956581 reaction equation
C(F)(F)=C(Cl)F.[CH3:7][O:8][C:9]1[CH:10]=[CH:11][C:12]2[O:18][C:17]3[CH:19]=[CH:20][CH:21]=[CH:22][C:16]=3[CH:15]=[C:14]([C:23](O)=[O:24])[C:13]=2[CH:26]=1>C(OCC)(=O)C.CCCCCC>[CH3:7][O:8][C:9]1[CH:10]=[CH:11][C:12]2[O:18][C:17]3[CH:19]=[CH:20][CH:21]=[CH:22][C:16]=3[CH:15]=[C:14]([CH2:23][OH:24])[C:13]=2[CH:26]=1

Participants

4

Reactant 2

HCID 6594ChlorotrifluoroethyleneHCID 18663613HCID 18663613, compound

Product 1

HCID 18663612HCID 18663612, compoundYield 96%

Reagents, catalysts & solvents 1

HCID 21226206Ethyl acetate hexaneSolvent

Procedure

Preparation analogous to Example 12 f) from 8-methoxy-dibenz[b,f]oxepine-10-carboxylic acid. Yield: 96% in the form of a brown oil; TLC (silica gel; ethyl acetate/hexane=1:1; UV): Rf =0.31; 1H-NMR (CDCl3, 300 MHz): 1.80 (sbr, 1H); 3.78 (s, 3H); 4.69 (s, 2H); 6.82-7.33 (m, 8H); MS: 254 (M+), 211, 182, 181 168, 165. 153, 152.

Sources & evidence

ORD record
ord-93193b3be4b848ce96d0d8b5f631f316
Source dataset
uspto-grants-1998_07
Patent number
US05780500

Reaction notes

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