HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-tert-Butylphenol → 2-[4-(Tert-Butyl)Phenoxy]Benzenecarbaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-tert-Butylphenol | HCID 7393 | — |
| Reactant | o-Fluorobenzaldehyde | HCID 67970 | — |
| Product | 2-[4-(Tert-Butyl)Phenoxy]Benzenecarbaldehyde | HCID 2763426 | 77% |
Reaction Steps
Preparation analogous to Example 12a) from 2-fluoro-benzaldehyde and 4-tert-butylphenol. Yield: 77%, yellow oil after high vacuum distillation (93°-100° C., 0.9 mbar); TLC (silica gel; hexane/ethyl acetate=1:1; UV): Rf =0.65; 1H-NMR (CDCl3, 200 MHz): 1.35 (s, 9H); 6.75-7.55 (m, 7H); 7.92 (dd, 1H) MS: 254 (M+), 239.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05780501 |
| Source dataset | uspto-grants-1998_07 |
| ORD ID | ord-af48c71dcdae43d4a692693e6b0e4068 |
| Source note | uspto-grants-1998_07 |